![]() The partial charge on the polar compound is Polar compound, m, its dipole moment, E µ Q m/d 2. Interaction between the full charge of an ion, Q, and the partial charge of a Separate the positive and negative ions from their positions in the crystalline Which have lost electrons, and full negative charges on the anions, which haveįeatures of salts is their extremely high melting points. In salts, there are full positive charges on the cations, The charges, Q 1 and Q 2, divided by the distance squared,ĭ 2. Law states that the potential energy, E is proportional to the amplitude of Strength of the IMF will, then, depend on the magnitude of these charges. KJ/mol and to break the remaining IMF in the vaporization of waterĪll IMF are electrostatic in nature, the interaction of To break the IMF in ice (heat of fusion) requires 6.02 Substances with high IMF will have higher melting and boiling Of vaporization (heat required to vaporize a liquid) are determined by the Kinetic energy of the gas molecules, as predicted by the Molecular Kinetic The remaining hydrogen bonds are broken, and all of the water moleculesĪre now moving independently of each other, with no remaining hydrogenĪddition of heat raises the temperature of the steam and increases the average At this temperature, the water, at 100 oC, There is a second phase transition at 100 oC. Hydrogen bonding between molecules, but they are no longer in fixed positions The movement of the water molecules will increase in the liquid L), addition of heat will then lead to an increase in temperature of the liquidĪgain, an increase in the KE of the system. Transition temperature, 0 oC, all of the ice will be converted to liquid It is the attraction between the partial positive charges on the H and theĭiscussed earlier in the semester, these are hydrogen bonds, holding the water molecules in the crystalline It is coulombic in nature, arising from the attraction of charged This is the energy associated with the IMF, which are holding the H 2O Temperature, the added energy goes to changing the Potential Energy of the system. The melting point of ice, further addition of heat does not change the temperature. Substance is unique, and depends on the chemical nature of the substance. Of ice, the heat required to change the temperature of 1 gram of ice by 1 oC. The amount of heat required to raise the temperature of the The bond lengths and angles are oscillating Mu 2) which is proportional to the absolute temperature (K) of theĬase of water, the O-H bonds are stretching and bending. The heat that we are adding is increasing the In this Heating Curve, we are starting withĪs we add heat, we raise the temperature of the ice. Time span, the more heat has been added to the system. The time axis represents the addition of heat The transitions between the phases, phase changes, can be viewed in terms of a Heating Curve, like the one shown below, for water. In solids, the molecules vibrate about fixed Liquids, the molecules slide past each other freely. ![]() In the gaseous phase, molecules are in random The IMF govern the motion of molecules as well. Intermolecular forces (IMF) are the forces which cause real gases toĪre also responsible for the formation of the condensed phases, solids and liquids. Of its container and is extremely compressible. Steam will assume both the shape and volume As solid ice, H 2O possesses a definiteĭefinite volume, but will assume the shape of its container. Properties of H 2O are very different in the three states. The same, the molecular shape is the same and the hybridization of the oxygen In all three cases, the bond angles are the same, the dipole moment is In its three forms, ice, water and steam. Intermolecular forces exist between molecules and influence the (bonding forces) exist within molecules and influence the chemical
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![]() 250–900 CE) defines the highest point of Maya civilization in architecture, art, writing, and population size. 1000 BCE corresponds to the Middle and Late Preclassic eras. ![]() 2000–1000 BCE) pre-dates the rise of the first kingdoms, so the span that began by ca. The Preclassic includes the origins and apogee of the first Maya kingdoms from about 1000 BCE to 250 CE. To understand and follow this long development, Maya civilization is divided into three periods: the Preclassic, the Classic, and the Postclassic. Most of these kingdoms existed for hundreds of years a few endured for a thousand years or more. Over the following 2,500 years scores of Maya polities rose and fell, some larger and more powerful than others. The brutal subjugation of the Maya people by the Spanish extinguished a series of independent Maya states with roots as far back as 1000 BCE. Located in eastern Mesoamerica, the ancient Maya flourished in a diverse homeland in Mexico, Guatemala, Belize, Honduras, and El Salvador until the Spanish Conquest. Maya civilization was part of this independent evolutionary process. ![]() Ancient raised fields at Pulltrouser Swamp in Belize are shown in this aerial photograph. He Maya produced bountiful harvests of food from a diverse and productive agricultural system that included irrigation, terracing, and drained fields in swamps and shallow lakes. This map shows the location of various sites mentioned in this issue of Expedition. Maya sites that have been identified and explored are located in Mexico, Guatemala, Belize, Honduras, and El Salvador. In fact, the evidence clearly shows that civilization evolved in the Americas due to the efforts of the descendants of the first people who came to the New World during the last Ice Age, some 12,000 to 20,000 years ago. Of course archaeology has found no evidence to suggest that Old World intrusions brought civilization to the Maya or to any other Pre-Columbian society. Consequently, 16th century Europeans readily accepted the myth that the Maya and other indigenous civilizations were transplanted to the Americas by “lost” Old World migrations before 1492. But 500 years ago, after the Spaniards “discovered” the Maya, many could not believe that Native Americans had developed cities, writing, art, and other hallmarks of civilization. The ancient Maya created one of the world’s most brilliant and successful civilizations. ![]() It runs on both 32-bit and 64-bit systems with no dedicated 64-bit download provided. Previous versions of the operating system shouldn't be a problem with Windows 8, Windows 7 and Windows Vista having been tested. Just go to the developers website and click on the Download button. SpeedCrunch can be used on a computer running Windows 11 or Windows 10. Most of our users download and install our apps through the Platforms built-in app store and then keep them updated using the platforms built. SpeedCrunch can be installed on Windows, MacOS, and Linux ( Flathub) operating systems. What version of Windows can SpeedCrunch run on? The source code for SpeedCrunch should be freely available and modifications are certainly permitted as well as the option to inspect the software. The license provides the options to freely download, install, run and share this program without any restrictions. SpeedCrunch has been released under the open source GPL license on Windows from calculators. Support for variables, e.G try x=pi/3 and then sin(x).Ohjelma toimii myös Windows ja MacOS -koneissa, niinpä sitä voi käyttää myös laskimena lukion matikan kursseilla. ![]() Esitän tässä muutamia ohjelman käyttöön liittyviä huomioita. Special variable ans holds the last calculation result. 1.2.22 korjasin näppäilyvihreitä Abittissa toimiva Speedcrunch on ihan näppärä apuohjelma matikan ylioppilaskokeen A-osassa.Postfix operator ! Lets you compute factorials.History of last expressions (use up and down arrow).High precision, up to 50 decimal digits.Built-in functions: abs, sqrt, pi, log, exp, ln, sin, cos, tan, sinh, cosh, tanh, asin, acos, atan, arsinh, arcosh, artanh. Apps Accessories Calculator Icon Image - Speedcrunch Icon Clipart is high quality 600600 transparent png stocked by PikPng.Angle mode: alt+d for degrees, alt+r for radians.The keyboard operation works well without long training and, above all, much faster than working with the mouse. SpeedCrunch is a powerful calculator that solves formulas and functions quickly. Chocolatey integrates w/SCCM, Puppet, Chef, etc. It's not a typical pocket calculator: Instead of the usual keys, the program welcomes you with a simple input line in which you type in all the calculations - this works intuitively and quickly in practice. Chocolatey is software management automation for Windows that wraps installers, executables, zips, and scripts into compiled packages. SpeedCrunch also allows the use of variables, understands the systems decimal, binary, octal and hexadecimal as well as the angular dimensions radians and degrees. When entering calculations, this freeware supports you with syntax highlighting and a preview of the result. SpeedCrunch incorporates lists with functions, constants, variables, volume and area formulas for objects, and intelligent auto-completion. ![]() It's the ultimate tool for performing all kinds of mathematical calculations. SpeedCrunch is a powerful algebraic calculator that you can use to solve even complex functions. Advanced scientific calculator with many built-in math functions. Instead of accusing your customers, you should put your cameras on the ones doing the massages. After I calmed down, I realized she was accusing me of stealing the card. Me, upset and not thinking, said whatever and walked out. She said she would send an email to her boss about the situation. She said, well we have cameras and saved records of where this card came from. I told her, again, there should be one hour on that card. What did that matter? How can she remember me from September? Again what does that matter. She continued to argue about what time I was there. As of April I started getting off at 2: 00. I come straight from work, since it’s down the street. I told her that wasn’t possible because I use to get off at 3: 30. She said she remembered me and I was there about the same time the last visit. The girl that gave it to me wrote my name. She said, I didn’t write your name on this card. How is that possible? I just got the card at my last visit. One on in 2013 and one in September of 2015. The girl at the desk said it was no good. She went behind the desk and brought me back a gift card. She took her tip from me and said I could get my next massage for a discounted rate, but I had to pay that day. I’m sorry, I tip based on service) The girl walked me towards the front and stopped by some shutter doors. As I was leaving, the girl that did my massage was waiting for her tip. The last time I was there, I only purchased an hour. My whole image of this place changed because of the RUDE lady at the front desk. I had great service and a relaxing message every time. The treatment ends with a face and neck massage.I have been to this place several times. Deep cleansing, exfoliation, vapor spray, blackhead removal, and eyebrow shaping are also done during the procedure. This treatment is performed by applying sound waves to generate pressure on deep skin tissue. A skin refresher and purifying mask, as well as a skin healing gel, is also applied. This treatment effectively inhibits excessive skin hormones with special organic acids, zinc, and vitamins. ![]() ![]() This treatment utilizes lotions with alpha-hydroxy acids, urea peroxide, and salicylic acid for cleansing skin of whiteheads and blackheads. Your hands will be treated with cleansing, exfoliation, hydrating lotions, and creams with heated gloves on both hands ending with a hand massage. This treatment combines our Basic Facial with the addition of skin care for your hands. ![]() Your face will undergo a steam treatment, cleansing and exfoliation, a hydrating treatment with a facial mask is then applied, concluding with a face and neck massage. Our facials are tailored to help make your facial skin look healthier, renew, rejuvenated, and more beautiful. When these specific areas are massaged, a tremendous feeling of relaxation results with increased circulation and lymphatic flow. Massage performed by applying varying pressure with the fingers, elbows, or palms to specific areas on the skin to trigger points for therapeutic effects. After the salt scrub a shower is then taken followed by a relaxing and soothing massage. This unique massage is performed by scrubbing your back using a special sea salt mixed with aromatic oils to exfoliate and hydrate the skin. When you inhale the essential oils, a chemical signal is sent to the brain to therapeutically treat the body and mind. The essential oils are specifically chosen by your masseuse to stimulate your olfactory (smell) system to achieve a desired emotional state of the mind. Soothing massage using different essential oils in combination with Swedish or Deep Tissue massage. Then massage of the relaxed muscles help to revitalize the tensed muscle and inflamed connective tissue to full health. The heated stones relieve stiffness and soreness in the back muscles and surrounding joints. Massage that consists of placing smooth heated stones at strategic places on the back. The benefits of stress reduction are well known and documented in the scientific literature. By stimulating nerves in the foot it leads to relaxation and stress reduction that to better overall health. Massage focusing on the feet to stimulate, rejuvenate, and reduce stress. We provide the following Dayspa services: Full Body Massage Facials Waxing Infrared Sauna Treatments Foot Reflexology The search for a hidden planet, pushing and pulling on the distant reaches of the solar system dates back to at least the late 19th Century when Percival Lowell founded an observatory in Arizona. RELATED: Is there a ghost planet hiding in the shadows behind Neptune? For more than a century, astronomers both amateur and professional have suggested the potential existence of an as-yet-undiscovered planet beyond the orbit of Neptune. In fact, there might be entire planets out there, shaking up our gravitational neighborhood right beneath our noses. It wouldn’t be the first time that an invisible force from beyond the stars influenced our little neck of the cosmic woods, and it won’t be the last. It’s a horrifying reminder that sometimes the answers to the mysteries which most plague us are right in front of us, if only we have the tools to see them. Spoiler warning! It begins with lights in the forest and ends with a visitation from an extraterrestrial entity who reveals the true and grisly nature of Maisie’s disappearance. After a year with no sign of her, they presume Maisie dead and hold a funeral, but that’s when some truly strange things start happening. ![]() The 2019 science fiction thriller Dark Encounter (now streaming on Peacock!) starts in the winter of 1982 when Ray and Olivia return to their home and find that their 8-year-old daughter Maisie is missing. You – the person we’ve opened an account for. You'll also be issued with a password or unique code that keeps your details secure.These Terms and Conditions set out the agreement between: ![]() You'll still be issued with a card to withdraw cash, but you'll be able to check your balance and statements online 24 hours a day. You probably need to be over 18 to apply for one, but the convenience of being able to do the vast majority of your banking through your computer might be really convenient. You may want to open an account with an internet only bank. You may also be able to apply for high street accounts online, but if banking is new to you and it's your first account, it's better to go into your branch and get your questions answered. If you're under 16 and you don't have any of these, you may be able to use your parents' details - as long as they go with you. ![]() You may also need some form of identification, so remember to bring your passport, birth certificate or proof of address with you. If you're under 16, you may need parental permission, so go with one of your parents. To apply for a current account, you'll need to go to your local branch and speak to a customer adviser. If you find a better account with a different bank to the one you're using now, move it over as soon as possible. They often offer low-interest overdrafts and discounts on contents insurance and transport.Īs with any other account, the best account for you will depend on your personal circumstances. If you're studying at university, you'll find that lots of banks offer accounts that are tailored to the needs of students. When you're choosing your account, the rate of interest is an important reason to consider but if you do want to save your money, you'd be better off looking at savings accounts instead of current accounts. You'll also be paid interest on your money, depending on how much money you put into your account and how long it stays there. Most accounts will give you a card that you can use to withdraw money through a cash machine, but you may not receive a debit card or a cheque book that you can use to pay for goods until you're 16.Ĭertain internet banks don't allow under 18s to open an account through them and you won't be able to get an overdraft until you're 18. You should also check whether your account can be managed on the telephone and whether it has a 24 hour customer service line. Make sure that the account is convenient for you. Although the idea of a new MP3 player or money off vouchers at high street stores can seem like a great idea, you shouldn't choose an account on the amount of freebies you get. You should be allowed to open an account from the age of 11, but you may not get certain benefits like a cheque book until you're older.īanks might offer free gifts and discounts to make their accounts sound the most appealing. ![]() Whatever you want to do, the first thing you should check is how old you have to be to open the account. ![]() you want to be able to pay for your shopping by using a card.you want easy access to your money 24 hours a day.There are hundreds of accounts to choose from, but to find out which is the best for you, think about the things you'll be using the account for: This means that you won't have to worry about missing any payment deadlines as your bills are paid automatically. You can also set up standing orders and Direct Debits from a current account for the regular payments that you have to make, like your mobile phone bill. Current accounts are just another name for a simple bank account and they allow you to withdraw money from a cash machine, transfer money to other accounts and earn interest on your cash.Īlthough you may already have a savings account set up in your name, current accounts allow you to control what goes in and out of your own account more closely. If you've grown out of putting money in a piggy bank, it's likely that you're ready to open a current account. There's a range of current accounts available, but shopping around to find out which one suits you best is vital What a current account is If you're earning a wage or claiming benefits, you'll probably need a bank account. ![]() Originally introduced with NS7, this incredible virtual-needle-drop technology allows you to locate any point on a track by using an advanced touch strip on each deck. 4TRAK makes it possible to take music from virtually any source and bring it into your mix.ĤTRAK is a complete DJ controller, able to handle everything you’ve got, empowering you to perform at your highest level.ĤTRAK includes the groundbreaking Numark innovation known as Strip Search. Grab tracks or loops from your music library one moment, then your turntable, iPod, or a mic the next. Connect two CD players, two turntables, two mics-the combinations are endless. ![]() "…the platters are simply the most solid I have ever used on a controller….I would go as far as to say this is probably the best dedicated software controller I have used to date." - Įach of 4TRAK’s channels has an input selector, so you can instantly transition between controlling Traktor's four decks and your external sources. Each FX deck also features time division controls, allowing you to match your effects to a track's BPM instantly, and giving you continuous control over an effect's pacing. Both the FX1 and FX2 decks give you three controls that can be assigned to the effects of your choice. Layer effects, adjust filters, and mix and match both of them in ways that were previously impossible.ĤTRAK's FX KOMMAND CONSOLE gives you two decks of effects controls, FX1 and FX2, plus four detented filter knobs for each of 4TRAK's four channels. With the FX KOMMAND CONSOLE, you have top-level access to effect and filter parameters, giving you incredible performance capabilities. Connect almost any external music source like turntables, CD players and microphones, and mix them in seamlessly with tracks from your software.ĤTRAK offers unparalleled control over your effects and filters. 4TRAK has a full range of input and outputs for connecting virtually any device: RCA inputs on each channel and four line-level inputs with two switchable to phono and two switchable to mic. Tweak everything: High-resolution platters, exclusive Strip Search needle-drop technology and an expansive 12-knob FX KOMMAND CONSOLE give you more precise control over Traktor than ever before.Īt the heart of 4TRAK is a premium-quality fully independent four-channel mixer that can be used with or without a computer, making 4TRAK one of the most versatile Traktor controllers in the world. Mix anything: 4TRAK's built-in four-channel mixer allows you to bring turntables, microphones, MP3 players and more into the mix. 4TRAK lays out a vast assembly of tactile controls in front of you, putting a playground of capability at your fingertips. Plus Mixtrack II operates via standard MIDI, so it’s compatible with virtually any popular DJ software.Įxperience your music like never before with Mixtrack II from Numark.Four decks of software control, a four-channel mixer and total command over all effects: Meet 4TRAK, the ultimate controller for Traktor DJ software. ![]() Start mixing right away-with the included Virtual DJ LE software you can create professional sounding mixes at home or easily upgrade to Virtual DJ Pro for performing live at parties, functions, and clubs. Get precise control over every track and every transition with Mixtrack II’s advanced low-profile platters. Both are capacitive and dual-zone, giving you the ability to scratch or stop a track simply by touching the top of the platter, while at the same time allowing you to adjust the pitch by manipulating the platter from the side. Pitch and Sync controls are onboard for seamless and easy mixing as well as 16 dedicated effects controls. You’ll be able to spend more time interacting with the music and less time staring at the computer screen. Mixtrack II’s new slimline low-profile design is made to be played with a complete mixer section, precise crossfader, 3-band EQ, and dedicated music library navigation controls. Create loops, launch samples, and control hot cues with the 16 backlit rubber drum pads. Instantly switch between Loop Mode, Sample Mode, and Hot Cue Mode. Mixtrack II comes tailor-made for dynamic performance. Add effects like flanger, phaser, and echo, and experience your music like never before. ![]() Get your hands on Mixtrack II’s extensive layout of DJ controls, which includes automatic beat sync, hot cues, and looping. Connect to your computer and start DJing today Mixtrack II comes with Virtual DJ LE software so you can start mixing right away. Start mixing today with a cutting-edge DJ system from the world's #1 DJ brand.įrom Numark, the world’s leading creator of DJ technology, comes Mixtrack II-now with a streamlined design and an expanded layout of professional controls, including 16 backlit multifunction drum pads and illuminated touch-activated platters. ![]() The patrolling ones around the Water Treatment Plant are also uncommon and are probably the most dangerous unless you can take your time and spot them from a distance. Their spawns can fluctuate, so the ones in the main gate and warehouse rooftops are more reliable. The Rogues on the rooftops are dangerous because they can laser into your location even from afar, as long as they have an angle.įor the Rogues inside the warehouses, they are more uncommon, and from experience, they spawn more inside warehouse 1. One by each mounted gun and one by the big container next to the main road.įor the warehouses, the Rogue spawns can be extremely random, but you can bet that more than three Rogues can spawn on all rooftops as a minimum.Įach warehouse can spawn one to three Rogues, so there can even be a total of nine Rogues on all rooftops, excluding the ones on the main gate, the ones patrolling outside, and the ones inside the warehouses. You should always be careful because there is even a possibility that three Rogues spawn here. The Rogues spawn on the mounted guns in the main gate, but there is a possibility that only one Rogue spawns here. The most common places that Rogues spawn on are the following. There are a ton of Rogues to loot, but if you are thinking of finding more than ten Rogues to kill in a single raid, it will be an extremely rare case, even if you go through all the locations. The Rogues in Lighthouse can spawn in a lot of different locations, and their quantity is quite random as well. Rogue Loot Drops Rogues’ Location and Behavior ![]() ![]() He received his EdD at Teacher's College, Columbia University his studies there focused on learning theories and jazz pedagogy. He holds both a Bachelor of Music (Jazz) and Master of Arts in Teaching degrees from the University of the Arts in Philadelphia. Wetzel is Assistant Professor of Music and Director of Jazz Studies at Moravian College his duties include teaching saxophone, directing the Moravian College BIG Band, and overseeing the jazz studies program. When not on the road with the EMQ, Nelson is father to his 4 daughters Jessica, Danielle, Talia and Kendall.ĭr. In 2002, Nelson became a Performing Artist and Clinician for the Yamaha Corporation of America. His students have enrolled in schools such as Eastman, Berklee, Ithica, NYU and Manhattan School of Music. Nelson has also taught saxophone and jazz improvisation at Lafayette College Blair Academy, and privately. Nelson released his second solo CD in the fall of 2004. He works with his quartet and with pianist Eric Mintel. In 2002, Nelson released his first solo CD titled Lethal. During his stay, he recorded on the albums Storm and Hollywood.Īfter he left Ferguson in 1984, Nelson worked at Tamiment Resort, Harrah's Marina and Mount Airy Lodge where he performed with Tony Bennett, The Spinners, The Temptations, Wayne Newton, Jay Black, Frankie Valli and many others. Upon graduation, he toured for three years with Maynard Ferguson, playing lead alto saxophone. He performed with the National Jazz Ensemble. At Eastman, Nelson studied with Ramon Ricker, Bill Dobbins, Rayburn Wright, William Osseck and Mardelle Marcellis. Nelson graduated from the Eastman School of Music in 1981 with a B.M. He has studied privately with Phil Woods, Hal Galper, Eddie Daniels and James Caruso. Nelson Hill is a saxophonist, clarinetist and flutist from Mt. ![]() ![]() Just is the scoundrel who plays the main role of the game, William Roehm, who has a talent to get into trouble while chasing glory and infamy. As a result, they combined both directions in a game that does not excel at anything: the puzzles feel out of place, the combat is really primitive, and the class system is too loose to have a meaningful impact.ĭespite this shortcomings, Quest for Infamy is more than just the sum of its parts and despite some design flaws it manages to be endearing. The developers of the game could not decide between making a quest type classic adventure focusing on puzzles and building an RPG with classes, attributes and a turn-based fighting system. Unfortunately, the game suffers from an identity crisis that makes it even harder to modern gamers to empathize with it. ![]() Every piece of the game radiates the developer’s love for the heroic age of quests and heroic adventures, presented with a humorous spin. Originally developed by a handful of people, Quest for Infamy is a trip back in time when game development was far from the standards we are used today. As you will see it is not just the graphics that show their age, but also the mechanics that are outdated. Now the time has come for console players to taste this game that is love a letter fueled by nostalgia to the RPGs and quests of the 90’s. Quest for Infamy is by no means a new game, and we are not referring to the classical art style, rather to the fact that it was released quite a few years ago on PC. |